Treatment of organic pollutants by homogeneous and heterogeneous Fenton reaction processes

Nowadays, the water ecosystem is being polluted due to the rapid industrialization and massive use of antibiotics, fertilizers, cosmetics, paints, and other chemicals. Chemical oxidation is one of the most applied processes to degrade contaminants in water. However, chemicals are often unable to completely mineralize the pollutants. Enhanced pollutant degradation can be achieved by Fenton reaction and related processes. As a consequence, Fenton reactions have received great attention in the treatment of domestic and industrial wastewater effluents. Currently, homogeneous and heterogeneous Fenton processes are being investigated intensively and optimized for applications, either alone or in a combination of other processes. This review presents fundamental chemistry involved in various kinds of homogeneous Fenton reactions, which include classical Fenton, electro-Fenton, photo-Fenton, electro-Fenton, sono-electro-Fenton, and solar photoelectron-Fenton. In the homogeneous Fenton reaction process, the molar ratio of iron(II) and hydrogen peroxide, and the pH usually determine the effectiveness of removing target pollutants and subsequently their mineralization, monitored by a decrease in levels of total organic carbon or chemical oxygen demand. We present catalysts used in heterogeneous Fenton or Fenton-like reactions, such as H₂O₂–Fe³⁺(solid)/nano-zero-valent iron/immobilized iron and electro-Fenton-pyrite. Surface properties of heterogeneous catalysts generally control the efficiency to degrade pollutants. Examples of Fenton reactions are demonstrated to degrade and mineralize a wide range of water pollutants in real industrial wastewaters, such as dyes and phenols. Removal of various antibiotics by homogeneous and heterogeneous Fenton reactions is exemplified.     

Thermal, Mechanical and Rheological Behavior of Poly(lactic acid)/Talc Composites

In the present study, influence of talc on thermal, mechanical and rheological behavior of PLA is investigated and the structure?Cproperty correlation for the PLA/talc composites is established. Poly(lactic acid)/talc composites are prepared by melt mixing of PLA with talc in twin screw extruder followed by blown film processing. Various characterizations techniques are used to evaluate thermal, morphological, mechanical and rheological behavior of PLA/talc composites and its blown film. DSC analysis showed that degree of crystallinity of PLA/talc composites was higher than that of neat PLA because of nucleating ability of talc. Spherulite morphology of PLA/talc composites showed that talc has increased nucleation density of spherulite having smaller radius than that of neat PLA. Talc is effective in enhancing tensile modulus and storage modulus of PLA due to reinforcing ability of talc particles.     

Diversification of nitrogen fixing bacterial community using nifH gene as a biomarker in different geographical soils of Western Indian Himalayas

Six soil samples (Pantnagar, Chamoli, Almora, Ranichauri, Pithoragarh and Badrinath) belonging to different geographical locations of Western Himalayas in India, were analyzed to diversify the nitrogen fixing bacterial community using nifH gene biomarker DNA from soil samples were isolated and amplified using nifH gene specific primers. Genomic DNA and PCR amplified products were then individually subjected to restriction digestion with tetra to octacutter enzymes (AluI, MspI, BgIII, XbaI, HindIII, HaeIII, AluI, MspI and PasI. Further restriction pattern was studied by preparing dendograms on the basis of similarity matrix and compared for the nifH community. It was observed that temperate region soils (Ranichauri and Pithoragarh) were negative for nifH marker while subalpine region (Badrinath) and tarai region soils (Pantnagar) documented similar nifH community. Moreover; the direct genomic DNA restriction analysis indicated that subalpine region soil (Badrinath) was most diversified.     

Catalytic advancements in carbonaceous materials for bio-energy generation in microbial fuel cells: a review

Environmental Science and Pollution Research - Microbial fuel cells (MFCs) are a sustainable alternative for wastewater treatment and clean energy generation. The efficiency of the technology is...     

Regression models to estimate total concentrations of polybrominated diphenyl ethers: data from NHANES 2003–2004

The objective of this study was to develop regression models to estimate the total concentration of polybrominated diphenyl ethers in serum based on the known concentrations of a limited number of congeners. Because of the possible adverse health effects associated with the exposure to polybrominated diphenyl ethers, it is of interest to know their total concentrations. Data from the National Health and Nutrition Examination Survey for 2003–2004 (N = 1859) were used to develop regression models to estimate both wet weight and lipid-adjusted total concentrations. Only the knowledge of three congeners, namely, 2,2′,4,4′-tetrabromodiphenyl ether, 2,2′,4,4′,5-pentadibromodiphenyl ether, and 2,2′,4,4′,5,5′-hexabromodiphenyl ether was required to use these models. Other than the concentrations of these three congeners, age, gender, and smoking status were the only information needed to use these models. Optionally, models were developed that could also use the race/ethnicity of the participants. All models explained more than 98% of the known variability in the observed total concentration levels. Over 98% of the model generated, predicted values were found to be within 5% of the observed values.     

Nitrate pollution of wells: pollution prevention policy options

Irrigated agriculture is a major sector of agricultural economy where high value crops are grown with substantial input of fertilizers and pesticides. High concentrations of nitrate and pesticides have been observed in ground water beneath irrigated areas in humid regions, where irrigation is practiced on sandy soils that have low water-holding capacity. Data from these areas indicate that irrigation wells are typically screened in the bottom part of the aquifer (which contain coarser deposits) whereas the domestic wells are screened just below the water table. Monitoring results from several irrigated areas have shown the stratification of dissolved inorganic and organic chemicals in the aquifer. Nitrate in such systems is typically highest near the surface. This has serious health implications for the rural population that relies upon shallow ground water for drinking. Current environmental policy towards pollution reduction focuses on improved management practices to reduce the loading of the chemicals to ground water. However, an engineering issue, dealing with the design of the irrigation and domestic wells has not been addressed. A design modification for the irrigation and domestic wells can reduce the risk of high nitrate ground water being pumped by domestic wells. A proposal to convert a deep vertical irrigation well to a series of small-capacity shallow vertical wells or a large-capacity horizontal well and slight deepening of the domestic wells was examined through simulations. This can reduce the nitrate concentration of ground water in domestic wells dramatically and use the high nitrate water for crop irrigation.     

Nitrate pollution of wells: pollution prevention policy options

Irrigated agriculture is a major sector of agricultural economy where high value crops are grown with substantial input of fertilizers and pesticides. High concentrations of nitrate and pesticides have been observed in ground water beneath irrigated areas in humid regions, where irrigation is practiced on sandy soils that have low water-holding capacity. Data from these areas indicate that irrigation wells are typically screened in the bottom part of the aquifer (which contain coarser deposits) whereas the domestic wells are screened just below the water table. Monitoring results from several irrigated areas have shown the stratification of dissolved inorganic and organic chemicals in the aquifer. Nitrate in such systems is typically highest near the surface. This has serious health implications for the rural population that relies upon shallow ground water for drinking. Current environmental policy towards pollution reduction focuses on improved management practices to reduce the loading of the chemicals to ground water. However, an engineering issue, dealing with the design of the irrigation and domestic wells has not been addressed. A design modification for the irrigation and domestic wells can reduce the risk of high nitrate ground water being pumped by domestic wells. A proposal to convert a deep vertical irrigation well to a series of small-capacity shallow vertical wells or a large-capacity horizontal well and slight deepening of the domestic wells was examined through simulations. This can reduce the nitrate concentration of ground water in domestic wells dramatically and use the high nitrate water for crop irrigation.     

An investigation into the acid content of aerosols in the ambient air at the Taj Mahal, Agra

A chemical analysis of suspended particulate matter (SPM) collected near the world famous Taj Mahal monument at Agra has been carried out. SPM samples collected on glass fibre filters were analysed for water-soluble sulphate, nitrate, chloride and ammonium ions. The data were derived from over 200 samples (each of 24 h), collected continuously during the winter periods (October through to March) of 1984-1985 and 1985-1986. The SO(4)(2-) and NO(3)(-) components are acidic in nature causing corrosion and effects on visibility, and so were studied in more detail. Mean values for SO(4)(2-) and NO(3)(-) derived from two-year data are 7.2 microg m(-3) and 8.2 microg m(-3), respectively. The SO(4)(2-)/SO(2) and NO(3)(-)/NO(2) ratiosobserved indicate faster conversion of SO(2) to SO(4)(2-) than NO(2) to NO(3)(-), the maximum levels being in January. Thus, both SO(4)(2-) and NO(3)(-) results appear to offer more promising indices of air quality than do SPM data alone.     

Analysis of willingness for relocation of the local communities living in the Critical Tiger Habitat of the Sariska Tiger Reserve,India

Many Indian Protected Areas (PAs) act as a support system for the communities living in and around them. Large-scale human interventions in these PAs have resulted in biodiversity loss, threat to wildlife and habitat fragmentation. The Sariska Tiger Reserve (STR) is no exception. In this reserve, tiger (Panthera tigris) became extinct in 2004.To create inviolate space for the reintroduced tigers, government has planned voluntary relocation of villages located inside Critical Tiger Habitat. The voluntary relocation plan will be more challenging if people are not willing to get relocated from PAs. Therefore, we have empirically analysed the identified factors influencing local communities’ willingness in getting relocated outside the STR using logit model. Results revealed that “restriction of access” and “market access” are the most influential factors and positively associated while forest dependency is negatively associated with local communities’ willingness. Based on these results, it was recommended that policy should be directed towards restriction on accessing forest resources along with reduction in forest dependency by nurturing and strengthening villagers’ livelihood to ensure successful relocation. Displacement of existed small markets around the reserve will also persuade them to relocate in areas more connected to market and other facilities.